Synthesis and study of coordinating agents for the synthesis of new coordination compounds
pdf

Keywords

bridging ligand
coordinating compound
synthesis
condensation
hydrazinecarboxamides
hydrazinecarbothioamides
carbonyl compound
IR spectrum
spectrophotometry
GAUSSIAN
theoretical calculations

How to Cite

Chiriac, G., & Codreanu , S. (2022). Synthesis and study of coordinating agents for the synthesis of new coordination compounds. Acta Et Commentationes Exact and Natural Sciences, 13(1), 100-109. https://doi.org/10.36120/2587-3644.v13i1.100-109

Abstract

Two compounds were obtained from the condensation reaction of semicarbazide (hydrazinecarboxamide) and semithiocarbohydrazide (hydrazinecarbothioamide) compounds with a 3-pyridinecarboxaldehyde carbonyl compound: (E)-1-(pyridin-3-ylmethylene)thiourea (L-1) and (E)-1-(pyridin-3-ylmethylene)urea (L-1) (L-2). The structure and composition of these compounds were determined using theoretical calculations with the GAMESS software package and IR spectroscopy. The new organic molecules L-1 and L-2 have the potential to be used as mono- or bidentate coordinating agents in the construction of coordination compounds with various useful properties.

https://doi.org/10.36120/2587-3644.v13i1.100-109
pdf
Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.